Author name: Prasanna

MCQ Questions for Class 12 Chemistry Chapter 9 Coordination Compounds with Answers

Students are advised to practice the NCERT MCQ Questions for Class 12 Chemistry Chapter 9 Coordination Compounds with Answers Pdf free download is available here. MCQ Questions for Class 12 Chemistry with Answers are prepared as per the Latest Exam Pattern. Students can solve these Coordination Compounds Class 12 MCQs Questions with Answers and assess their preparation level.

Coordination Compounds Class 12 MCQs Questions with Answers

Solving the Coordination Compounds Multiple Choice Questions of Class 12 Chemistry Chapter 9 MCQ can be of extreme help as you will be aware of all the concepts. These MCQ Questions on Coordination Compounds Class 12 with answers pave for a quick revision of the Chapter thereby helping you to enhance subject knowledge. Have a glance at the MCQ of Chapter 9 Chemistry Class 12 and cross-check your answers during preparation.

Question 1.
The coordination number of cobalt in [Co(en)3]3+ is
(a) 3
(b) 4
(c) 6
(d) 2

Answer

Answer: (c) 6


Question 2.
The IUPAC name of K3[Fe(CN)5NO] is
(a) potassium pentacyanonitrosylferrate(II)
(b) potassium pentacyanonitroferrate(II)
(c) potassium pentacyanonitrosylferrate(III)
(d) tripotassium pentacyanonitrosy If errate(II)

Answer

Answer: (a) potassium pentacyanonitrosylferrate(II)


Question 3.
Which of the following is hexadentate ligand?
(a) diene
(b) CN
(c) en
(d) EDTA

Answer

Answer: (d) EDTA


Question 4.
On adding AgNO3 solution to 1 mole of PdCl2. 4NH3 two moles of AgCl are formed. The secondary valency of Pd in the complex will be
(a) 0
(b) 2
(c) 4
(d) 1

Answer

Answer: (c) 4


Question 5.
What kind of isomerism exists between [Cr(H2O)6]Cl3 and [Cr(H3O)5Cl]Cl2. H2O?
(a) Linkage isomerism
(b) Solvate isomerism
(c) Ionisation isomerism
(d) Coordination isomerism

Answer

Answer: (b) Solvate isomerism


Question 6.
The IUPAC name of [PtCI(NO2) (NH3)4]SO4 is
(a) Tetraamminechloridonitrito-N- platinate (III) sulphate
(b) Tetraamminechloridonitrito-N- platinum (IV) sulphate
(c) Chloridonitrito-N- ammineplatinum(IV) sulphate
(d) Tetraamminechloridonitrito-N- platinate (IV) sulphate

Answer

Answer: (b) Tetraamminechloridonitrito-N- platinum (IV) sulphate


Question 7.
Which metal is present in vitamin B12 cyanocobalamin?
(a) Fe
(b) Co
(c) Mg
(d) Pt

Answer

Answer: (b) Co


Question 8.
Which is present in metal carbonyls?
(a) M-C σ bond
(b) M – C π bond
(c) M-C σ and M – C π bond
(d) None of these

Answer

Answer: (c) M-C σ and M – C π bond


Question 9.
How many ions are given by [Co(NH3)5 Br] Cl2 complex in water?
(a) 4
(b) 2
(c) 6
(d) 3

Answer

Answer: (d) 3


Question 10.
Which complex exhibits geometrical isomerism?
(a) [MnBr4]2+
(b) [Pt(NH3)3Cl]+
(c) [PtCl2(P(C2H2)3)2]
(d) [Fe(H2O)5NO]2+

Answer

Answer: (c) [PtCl2(P(C2H2)3)2]


Question 11.
The IUPAC name of K[Ag(CN)2] is
(a) dicyanidosilver(l)
(b) dicyanidoargentate(l)
(c) potassium dicyanidoargentate(l)
(d) potassium dicyanidoargentate(ll)

Answer

Answer: (c) potassium dicyanidoargentate(l)


Question 12.
The IUPAC name of the compound K2[Ni(CN)4] is
(a) Potassium tetracyanidonickelate(lll)
(b) Potassium tetracyanidonickelate(ll)
(c) Potassium tetracyanidonickel(lll)
(d) Potassium tetracyanidonickel(ll)

Answer

Answer: (b) Potassium tetracyanidonickelate(ll)


Question 13.
Which metal carbonyl has the strongest C-O bond?
(a) Mn(CO)6+
(b) Cr(CO)6
(c) V(CO)6
(d) Fe(CO)5

Answer

Answer: (a) Mn(CO)6+


Question 14.
In the following which metal complex ion has zero oxidation number?
(a) [Cr(H2O)6]3+
(b) [CuCl4]2-
(c) [Fe(CO)5]
(d) [Fe(CN)6]3-

Answer

Answer: (c) [Fe(CO)5]


Question 15.
In the following chelating ligand is
(a) OH
(b) H2NCH2CH2NH2
(c) Cl
(d) CN

Answer

Answer: (b) H2NCH2CH2NH2


Question 16.
What is the coordination number in the K3[Cr(C2O4)3] coordinate compound
(a) 3
(b) 6
(c) 4
(d) 2

Answer

Answer: (b) 6


Question 17.
What is the oxidation state of Fe in K3[Fe(CN)6]
(a) +2
(b) +3
(c) +4
(d) +1

Answer

Answer: (b) +3


Question 18.
K3[Al(C2O4)3] is named as
(a) potassium trioxalatoaluminate (III)
(b) potassium aluminooxalate
(c) potassium aluminium(lll) oxalate
(d) potassium trioxalatoaluminate (II)

Answer

Answer: (a) potassium trioxalatoaluminate (III)


Question 19.
Predict the number of ions produced per formula unit in an aqueous solution of [Co(en)3]Cl3.
(a) 4
(b) 3
(c) 6
(d) 2

Answer

Answer: (a) 4


Question 20.
When one mole of CoCl3.5NH3 was treated with excess of silver nitrate solution, 2 mol of AgCl was precipitated. The formula of the compound is:
(a) [Co(NH3)5Cl2]Cl
(b) [Co(NH3)5Cl]Cl2
(c) [Co(NH3)4Cl2] (NH3)Cl
(d) [Co(NH3)3Cl3] (NH3)2

Answer

Answer: (b) [Co(NH3)5Cl]Cl2


Question 21.
The absorption maxima of several octahedral complex ions are as follows:
MCQ Questions for Class 12 Chemistry Chapter 9 Coordination Compounds with Answers 1
The crystal field splitting is maximum for:
(a) [CO(H2O)6]3+
(b) [CO(CN)6]3-
(c) (CO(NH3)6]3+
(d) All the complex ions have the same splitting, Δ0.

Answer

Answer: (b) [CO(CN)6]3-


Assertion and Reason Type Questions

The questions given below consist of an assertion and a reason. Use the following key to choose the appropriate answer.
(a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).
(b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).
(c) Assertion (A) is correct, Reason (R) is wrong statement.
(d) Assertion (A) is wrong, but Reason (R) is correct statement.

Question 22.
Assertion: The complex [Co(NH3)3Cl3] does not give precipitate with silver nitrate solution.
Reason: The given complex is non-ionizable.

Answer

Answer: (a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).


Question 23.
Assertion: The complex ion trans [Co(en)2Cl2]+ is optically active.
Reason: It is an octahedral complex.

Answer

Answer: (b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).


Question 24.
Assertion: NF3 is weaker ligand than N(CH3)3.
Reason: NF3 ionises to give F ions in aqueous solution.

Answer

Answer: (c) Assertion (A) is correct, Reason (R) is wrong statement.


Question 25.
Assertion: The [Ni(en)3]Cl2 (en = ethylenediamine) has lower stability than [Ni(NH3)6]Cl2.
Reason: In [Ni(en)3]Cl2, the geometry of Ni is trigonal bipyramidal.

Answer

Answer: (d) Assertion (A) is wrong, but Reason (R) is correct statement.


Question 26.
Assertion: [Ni(CO)4] is diamagnetic and tetrahedral in shape.
Reason: [Ni(CO)4] contains no unpaired electron and involves dsp² hybridisation.

Answer

Answer: (c) Assertion (A) is correct, Reason (R) is wrong statement.


Question 27.
Assertion: The ligands -NO2 and ONO are ambident in nature.
Reason: They form linkage isomers.

Answer

Answer: (a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).


Question 28.
Assertion: The complex [Fe(CN)6]4- is diamagnetic though iron (II) has 3d6 configuration.
Reason: CN is a strong ligand and has the configuration: t2g6. Therefore, it has no unpaired electrons.

Answer

Answer: (a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).


Question 29.
Assertion: The oxidation state of Pt in Zeise salt is 0.
Reason: Zeise salt is non-ionic complex.

Answer

Answer: (c) Assertion (A) is correct, Reason (R) is wrong statement.


Question 30.
Assertion: Optical isomerism is not shown by square planar complexes.
Reason: Square planar complexes do not have chiral structures.

Answer

Answer: (a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).


Question 31.
Assertion: Tetrahedral complexes do not show geometrical isomerism.
Reason: Bond angle in tetrahedral geometry is 109.5°.

Answer

Answer: (b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).


Question 32.
Assertion: [Ni(CO)4] is diamagnetic complex.
Reason: It involves sp³ hybridisation and there is no unpaired electron.

Answer

Answer: (a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).


Question 33.
Assertion: The complex [Co(NH3)4Cl2]Cl gives precipitates corresponding to 2 mol of AgCl with AgNO3 solutions.
Reason: It ionises as [Co(NH3)4Cl2]+ + Cl.

Answer

Answer: (d) Assertion (A) is wrong, but Reason (R) is correct statement.


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MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers

Students are advised to practice the NCERT MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers Pdf free download is available here. MCQ Questions for Class 12 Chemistry with Answers are prepared as per the Latest Exam Pattern. Students can solve these Haloalkanes and Haloarenes Class 12 MCQs Questions with Answers and assess their preparation level.

Haloalkanes and Haloarenes Class 12 MCQs Questions with Answers

Solving the Haloalkanes and Haloarenes Multiple Choice Questions of Class 12 Chemistry Chapter 10 MCQ can be of extreme help as you will be aware of all the concepts. These MCQ Questions on Haloalkanes and Haloarenes Class 12 with answers pave for a quick revision of the Chapter thereby helping you to enhance subject knowledge. Have a glance at the MCQ of Chapter 10 Chemistry Class 12 and cross-check your answers during preparation.

Question 1.
The order of reactivity of the following alcohols with halogen acids is
(a) CH3CH2-CH2-OH
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 1
(a) (a) > (b) > (c)
(b) (c) > (b) > (a)
(c) (b) > (a) > (c)
(d) (a) > (c) > (b)

Answer

Answer: (b) (c) > (b) > (a)


Question 2.
Which of the following alcohols will yield the corresponding alkyl chloride on reaction with concentrated HCI at room temperature?
(a) CH3CH2-CH2-OH
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 2

Answer

Answer:
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 3


Question 3.
Identify the compound Y in the following reaction.
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 4

Answer

Answer:
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 5


Question 4.
Toluene reacts with a halogen in the presence of iron (iii) chloride giving ortho and para halo compounds. The reaction is
(a) Electrophilic elimination reaction
(b) Electrophilic substitution reaction
(c) Free radical addition reaction
(d) Nucleophilic substitution reaction

Answer

Answer: (b) Electrophilic substitution reaction


Question 5.
Which of the following is halogen exchange reaction?
(a) RX + Nal → Rl + NaX
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 6

Answer

Answer: (a) RX + Nal → Rl + NaX


Question 6.
Which reagent will you use for the following reaction?
CH3CH2CH2CH3 →CH3CH2CH2CH2Cl + CH3CH2CHClCH3
(a) Cl2/UV light
(b) NaCl + H2SO4
(c) Cl2 gas in dark
(d) Cl2 gas in the presence of iron in dark

Answer

Answer: (a) Cl2/UV light


Question 7.
Arrange the following compounds in the increasing order of their densities.
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 7
(a) (i) < (ii) < (iii) < (iv)
(b) (i) < (iii) < (iv) < (ii)
(c) (iv) < (iii) < (ii) < (i)
(d) (ii) < (iv) < (iii) < (i)

Answer

Answer: (a) (i) < (ii) < (iii) < (iv)


Question 8.
Arrange the following compounds in increasing order of their boiling points.
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 8
(a) (ii) < (i) < (iii)
(b) (i) < (ii) < (iii)
(c) (iii) < (i) < (ii)
(d) (iii) < (ii) < (i)

Answer

Answer: (c) (iii) < (i) < (ii)


Question 9.
In which of the following molecules carbon atom marked with asterisk (*) is asymmetric?
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 9
(a) (i), (ii), (iii), (iv)
(b) (i), (iii), (iii)
(c) (ii), (iii), (iv)
(d) (i), (iii), (iv)

Answer

Answer: (b) (i), (iii), (iii)


Question 10.
Which of the following structures is enantiomeric with the molecule (A) given below?
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 10

Answer

Answer:
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 11


Question 11.
Which of the following is an example of vic-dihalide?
(a) Dichloromethane
(b) 1,2-dichloroethane
(c) Ethylidene chloride
(d) Ally l chloride

Answer

Answer: (b) 1,2-dichloroethane


Question 12.
The position of -Br in the compound in CH3CH=CHC(Br)(CH3)2 can be classified as
(a) Allyl
(b) Aryl
(c) Vinyl
(d) Secondary

Answer

Answer: (a) Allyl


Question 13.
Chlorobenzene is formed by reaction of chlorine with benzene in the presence of AlCl3. Which of the following species attacks the benzene ring in this reaction?
(a) cl
(b) cl+
(c) AlCl3
(d) [AlCl4]

Answer

Answer: (b) cl+


Question 14.
Ethylidene chloride is a/an
(a) vic-dihalide
(b) gem-dihalide
(c) allylic halide
(d) vinylic halide

Answer

Answer: (b) gem-dihalide


Question 15.
What is ‘A’ in the following reaction?
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 12

Answer

Answer:
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 13


Question 16.
A primary alkyl halide would prefer to undergo
(a) SN1 reaction
(b) SN2 reaction
(c) α-Elimination
(d) Racemisation

Answer

Answer: (b) SN2 reaction


Question 17.
Which of the following alkyl halides will undergo SN1 reaction most readily?
(a) (CH3)3C-F
(b) (CH3)3C-Cl
(c) (CH3)3C-Br
(d) (CH3)3C-I

Answer

Answer: (d) (CH3)3C-I


Question 18.
Which is the correct IUPAC name for
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 14
(a) 1-Bromo-2-ethylpropane
(b) 1 -Bromo-2-ethyl-2-methylethane
(c) 1-Bromo-2-methylbutane
(d) 2-Methyl-1-bromobutane

Answer

Answer: (c) 1-Bromo-2-methylbutane


Question 19.
What should be the correct IUPAC name for diethylbromomethane?
(a) 1-Bromo-1,1-diethylmethane
(b) 3-Bromopentane
(c) 1-Bromo-1-ethylpropane
(d) 1-Bromopentane

Answer

Answer: (b) 3-Bromopentane


Question 20.
The reaction of toluene with chlorine in the presence of iron and in the absence of light yields
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 15
(d) Mixture of (b) and (c)

Answer

Answer: (d) Mixture of (b) and (c)


Question 21.
Chloromethane on treatment with excess of ammonia yields mainly
(a) N, N-Dimethylmethanamine
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 16
(b) N-methylmethanamine (CH3-NH-CH3)
(c) Methanamine (CH3NH2)
(d) Mixture containing all these in equal proportion

Answer

Answer: (c) Methanamine (CH3NH2)


Question 22.
Molecules whose mirror image is non- superimposable over them are known as chiral. Which of the following molecules is chiral in nature?
(a) 2-Bromobutane
(b) 1 -Bromobutane
(c) 2-Bromopropane
(d) 2-Bromopropan-2-ol

Answer

Answer: (a) 2-Bromobutane


Question 23.
Reaction of C6H5CH2Br with aqueous sodium hydroxide follows
(a) SN1 mechanism
(b) SN2 mechanism
(c) Any of the above two depending upon the temperature of reaction
(d) Saytzeff rule

Answer

Answer: (a) SN1 mechanism


Question 24.
Which of the carbon atoms present in the molecule given below are asymmetric?
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 17
(a) a, b, c, d
(b) b, c
(c) a, d
(d) a, b, c

Answer

Answer: (b) b, c


Question 25.
The IUPAC name of the compound shown below is:
MCQ Questions for Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes with Answers 18
(a) 2-bromo-6-chlorocyclohex-1 -ene
(b) 6-bromo-2-chlorocyclohexene
(c) 3-bromo-1-chlorocyclohexene
(d) 1 -bromo-3-chlorocyclohexene

Answer

Answer: (c) 3-bromo-1-chlorocyclohexene


Assertion and Reason Type Questions

The questions given below consist of an assertion and a reason. Use the following key to choose the appropriate answer.
(a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).
(b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).
(c) Assertion (A) is correct, Reason (R) is wrong statement.
(d) Assertion (A) is wrong, but Reason (R) is correct statement.

Question 26.
Assertion: Addition of Br2 to but-1-ene gives two optical isomers.
Reason: The product contains one asymmetric carbon atom.

Answer

Answer: (a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).


Question 27.
Assertion: SN2 reaction proceeds with inversion of configuration.
Reason: SN2 reactions occur in one step.

Answer

Answer: (b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).


Question 28.
Assertion: Addition of Br2 to trans-2- butene yields meso-2, 3-dibromobutane.
Reason: Bromine addition to an alkene is an electrophilic addition reaction.

Answer

Answer: (b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).


Question 29.
Assertion: Benzyl bromide when kept in acetone-water, it produces benzyl alcohol.
Reason: The reaction follows SN2 mechanism.

Answer

Answer: (c) Assertion (A) is correct, Reason (R) is wrong statement.


Question 30.
Assertion: The nucleophilic substitution of vinyl chloride is difficult than ethyl chloride.
Reason: Vinyl group is electron donating group.

Answer

Answer: (c) Assertion (A) is correct, Reason (R) is wrong statement.


Question 31.
Assertion: tert-butyl bromide undergoes SN1 nucleophilic substitution readily than n-butyl bromide.
Reason: It proceeds by the formation of stable carbocation.

Answer

Answer: (a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).


Question 32.
Assertion: Ethanol gives iodoform test while methanol does not.
Reason: Ethanol is less reactive than methanol towards nucleophilic addition reactions.

Answer

Answer: (b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).


Question 33.
Assertion: Treatment of chloroethane with a saturated solution of AgCN gives ethyl isocyanide as the major product.
Reason: Cyanide ion (:CN ) is an ambident nucleophile.

Answer

Answer: (b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).


Question 34.
Assertion: 2-Bromobutane on reaction with sodium ethoxide in ethanol gives 1-butene as the major product.
Reason: 1-Butene is less stable than 2-butene.

Answer

Answer: (d) Assertion (A) is wrong, but Reason (R) is correct statement.


Question 35.
Assertion: Alkyl iodide can be prepared by treating alkyl chloride/bromide with Nal in acetone.
Reason: NaCl and NaBr are soluble in acetone but Nal is not.

Answer

Answer: (c) Assertion (A) is correct, Reason (R) is wrong statement.


Question 36.
Assertion: Aryl halides undergo nucleophilic substitution reactions with ease.
Reason: The carbon halogen bond in aryl halides has partial double bond character.

Answer

Answer: (d) Assertion (A) is wrong, but Reason (R) is correct statement.


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MCQ Questions for Class 12 Chemistry Chapter 11 Alcohols, Phenols and Ethers with Answers

Students are advised to practice the NCERT MCQ Questions for Class 12 Chemistry Chapter 11 Alcohols, Phenols and Ethers with Answers Pdf free download is available here. MCQ Questions for Class 12 Chemistry with Answers are prepared as per the Latest Exam Pattern. Students can solve these Alcohols, Phenols and Ethers Class 12 MCQs Questions with Answers and assess their preparation level.

Alcohols, Phenols and Ethers Class 12 MCQs Questions with Answers

Solving the Alcohols, Phenols and Ethers Multiple Choice Questions of Class 12 Chemistry Chapter 11 MCQ can be of extreme help as you will be aware of all the concepts. These MCQ Questions on Alcohols, Phenols and Ethers Class 12 with answers pave for a quick revision of the Chapter thereby helping you to enhance subject knowledge. Have a glance at the MCQ of Chapter 11 Chemistry Class 12 and cross-check your answers during preparation.

Question 1.
Dehydration of tertiary alcohols with Cu at 573 gives
(a) Aldehydes
(b) Ketones
(c) Alkenes
(d) None of these

Answer

Answer: (c) Alkenes


Question 2.
Molecular formula of ethers is:
(a) CnH2n+2O
(b) CnH2nO
(c) CnH2n+1O
(d) None of these

Answer

Answer: (a) CnH2n+2O


Question 3.
Williamson’s synthesis is an example of:
(a) Nucleophilic substitution reaction
(b) Nucleophilic addition
(c) Electrophilic substitution
(d) None of the above

Answer

Answer: (a) Nucleophilic substitution reaction


Question 4.
Reaction used for the preparation of ethers is
(a) Reimer-Tiemann reaction
(b) Williamson’s synthesis
(c) Wurtz reaction
(d) Cannizzaro reaction

Answer

Answer: (b) Williamson’s synthesis


Question 5.
The test used to distinguish alcohols from one another is known as
(a) Hinsberg’s test
(b) 2, 4-DNP test
(c) Iodoform test
(d) Lucas Lest

Answer

Answer: (d) Lucas Lest


Question 6.
The IUPAC name of
MCQ Questions for Class 12 Chemistry Chapter 11 Alcohols, Phenols and Ethers with Answers 1
(a) Propane-1, 3-diol
(b) Propane-1, 2-diol
(c) Propane -1, 2, 3-triol
(d) Glycerol

Answer

Answer: (c) Propane -1, 2, 3-triol


Question 7.
Ethers on hydrolysis give
(a) carboxylic acid
(b) alcohol
(c) ester
(d) ketone

Answer

Answer: (b) alcohol


Question 8.
Which of the following has highest boiling point?
(a) Methanol
(b) Ethanol
(c) Propan-1 -ol
(d) Butan-1-ol

Answer

Answer: (d) Butan-1-ol


Question 9.
Which has highest value of pKa?
(a) Phenol
(b) Ethanol
(c) o-Nitrophenol
(d) o-Cresol

Answer

Answer: (b) Ethanol


Question 10.
Which of the following is most acidic?
(a) Benzyl alcohol
(b) Cyclohexanol
(c) Phenol
(d) m-Chlorophenol.

Answer

Answer: (d) m-Chlorophenol.


Question 11.
Phenols on reaction with cone. HNO3 in the presence of cone. H2SO4 give
(a) o-nitrophenol
(b) m-nitrophenol
(c) p-nitrophenol
(d) 2,4,6-trinitrophenol.

Answer

Answer: (d) 2,4,6-trinitrophenol.


Question 12.
Methanol and ethanol can be distinguished by using
(a) Fehling’s test
(b) Iodoform test
(c) Tollen’s test
(d) Carbylamine test.

Answer

Answer: (b) Iodoform test


Question 13.
The IUPAC name of the compound
MCQ Questions for Class 12 Chemistry Chapter 11 Alcohols, Phenols and Ethers with Answers 2
(a) 2-Chloro-3,4-dimethyl-n-pentyl alcohol
(b) 2-Chloro-3,4-dimethylpentan-5-ol
(c) 4-Chloro-2,3-dimethylpentan-1 -ol
(d) 2,3-Dimethyl-4-chloropentan-1 -ol.

Answer

Answer: (c) 4-Chloro-2,3-dimethylpentan-1 -ol


Question 14.
MCQ Questions for Class 12 Chemistry Chapter 11 Alcohols, Phenols and Ethers with Answers 3
A will be
(a) CH2=CH2
(b) C2H5OCH3
(c) (C2H5)2O
(d) CH3CH2CH2CH3

Answer

Answer: (c) (C2H5)2O


Question 15.
Which is weakest acid in the following?
(a) CH3OH
(b) (CH3)2CHOH
(c) CH3CH2OH
(d) (CH3)3COH

Answer

Answer: (a) CH3OH


Question 16.
Williamson synthesis is used to prepare:
(a) Alcohol
(b) Amine
(c) Ketone
(d) Ether

Answer

Answer: (d) Ether


Question 17.
In the reaction
MCQ Questions for Class 12 Chemistry Chapter 11 Alcohols, Phenols and Ethers with Answers 4
A and B are:
(a) C6H5l, CH3OH
(b) C6H5OH, CH3l
(c) C6H5CH2OH, CH3l
(d) CH3CH2l, C6H5OH

Answer

Answer: (b) C6H5OH, CH3l


Question 18.
The IUPAC name of
MCQ Questions for Class 12 Chemistry Chapter 11 Alcohols, Phenols and Ethers with Answers 5
(a) 2-Cyclopropoxybutane
(b) 2-Propoxybutane
(c) 2-Propoxypropane
(d) 2-Methyl-2-propoxypropane

Answer

Answer: (a) 2-Cyclopropoxybutane


Question 19.
Neutral ferric chloride test can be used to distinguish between
(a) Alcohols and ethers
(b) Aldehydes and ketones
(c) Amines and aldehyde
(d) Phenols and alcohols

Answer

Answer: (d) Phenols and alcohols


Question 20.
On reaction with aqueous bromine at room temperature, phenol forms which of the following?
(a) meta-Bromophenol
(b) 2, 6-Dibromophenol
(c) 2, 4, 6-Tribromophenol
(d) 3, 5-Dibromophenol

Answer

Answer: (c) 2, 4, 6-Tribromophenol


Question 21.
How many alcohols with molecular formula C4H10O are chiral in nature?
(a) 1
(b) 2
(c) 3
(d) 4

Answer

Answer: (a) 1


Question 22.
What is the correct order of reactivity of alcohols in the following reaction?
MCQ Questions for Class 12 Chemistry Chapter 11 Alcohols, Phenols and Ethers with Answers 6
(a) 1° > 2° > 3°
(b) 1° < 2° > 3°
(c) 3° > 2° > 1°
(d) 3° > 1° > 2°

Answer

Answer: (c) 3° > 2° > 1°


Question 23.
CH3CH2OH can be converted into CH3CHO by
(а) catalytic hydrogenation
(b) treatment with LiAlH4
(c) treatment with pyridinium chlorochromate
(d) treatment with KMnO4

Answer

Answer: (c) treatment with pyridinium chlorochromate


Question 24.
The process of converting alkyl halides into alcohols involves
(a) addition reaction
(b) substitution reaction
(c) dehydrohalogenation reaction
(d) rearrangement reaction

Answer

Answer: (b) substitution reaction


Question 25.
Which of the following compounds is aromatic alcohol?
MCQ Questions for Class 12 Chemistry Chapter 11 Alcohols, Phenols and Ethers with Answers 7
(a) A, B, C, D
(b) A, D
(c) B, C
(d) A

Answer

Answer: (c) B, C


Question 26.
Give IUPAC name of the compound given below.
MCQ Questions for Class 12 Chemistry Chapter 11 Alcohols, Phenols and Ethers with Answers 8
(a) 2-Chloro-5-hydroxyhexane
(b) 2-Hydroxy-5-chlorohexane
(c) 5-Chlorohexan-2-ol
(d) 2-Chlorohexan-5-ol

Answer

Answer: (c) 5-Chlorohexan-2-ol


Question 27.
IUPAC name of m-cresol is
(a) 3-methylphenol
(b) 3-chlorophenol
(c) 3-methoxyphenol
(d) benzene-1,3-diol

Answer

Answer: (a) 3-methylphenol


Question 28.
IUPAC name of the compound
MCQ Questions for Class 12 Chemistry Chapter 11 Alcohols, Phenols and Ethers with Answers 9
(a) 1-methoxy-1-methylethane
(b) 2-methoxy-2-methylethane
(c) 2-methoxypropane
(d) isopropylmethyl ether

Answer

Answer: (c) 2-methoxypropane


Question 29.
Which of the following species can act as the strongest base?
(a) ΘOH
(b) ΘOR
(c) ΘOC6H5
MCQ Questions for Class 12 Chemistry Chapter 11 Alcohols, Phenols and Ethers with Answers 10

Answer

Answer: (b) ΘOR


Question 30.
Which of the following compounds will react with sodium hydroxide solution in water?
(a) C6H5OH
(b) C6H5CH2OH
(c) (CH3)3COH
(d) C2H5OH

Answer

Answer: (a) C6H5OH


Question 31.
Phenol is less acidic than
(a) ethanol
(b) o-nitrophenol
(c) o-methylphenol
(d) o-methoxyphenol

Answer

Answer: (d) o-methoxyphenol


Question 32.
Which of the following is most acidic?
(a) Benzyl alcohol
(b) Cyclohexanol
(c) Phenol
(d) m-Chlorophenol

Answer

Answer: (d) m-Chlorophenol


Question 33.
Mark the correct order of decreasing acid strength of the following compounds.
MCQ Questions for Class 12 Chemistry Chapter 11 Alcohols, Phenols and Ethers with Answers 11
(a) E>D>B>A>C
(b) B>D>A>C>E
(c) D>E>C>B>A
(d) E>D>C>B>A

Answer

Answer: (b) B>D>A>C>E


Question 34.
Mark the correct increasing order of reactivity of the following compounds with
MCQ Questions for Class 12 Chemistry Chapter 11 Alcohols, Phenols and Ethers with Answers 12
(a) (i) < (ii) < (iii)
(b) (ii) < (i) < (iii)
(c) (ii) < (iii) < (i)
(d) (iii) < (ii) < (i)

Answer

Answer: (c) (ii) < (iii) < (i)


Question 35.
Arrange the following compounds in increasing order of boiling point.
Propan-1-ol, butan-1-ol, butan-2-ol, pentan-1-ol
(a) Propan-1-ol, butan-2-ol, butan-1-ol, pentan-1-ol
(b) Propan-1-ol, butan-1-ol, butan-2-ol, pentan-1-ol
(c) Pentan-1-ol, butan-2-ol, butan-1-ol, propan-1 -ol
(d) Pentan-1-ol, butan-1-ol, butan-2-ol, propan-1 -ol

Answer

Answer: (a) Propan-1-ol, butan-2-ol, butan-1-ol, pentan-1-ol


Assertion and Reason Type Questions

The questions given below consist of an assertion and a reason. Use the following key to choose the appropriate answer.
(a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).
(b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).
(c) Assertion (A) is correct, Reason (R) is wrong statement.
(d) Assertion (A) is wrong, but Reason (R) is correct statement.

Question 36.
Assertion: C2H5OH is a weaker base than phenol but is a stronger nucleophile than phenol.
Reason: In phenol the lone pair of electrons on oxygen is withdrawn towards the ring due to resonance.

Answer

Answer: (d) Assertion (A) is wrong, but Reason (R) is correct statement.


Question 37.
Assertion: The boiling points of alcohols are higher than those of hydrocarbons of comparable molecular mass.
Reason: Alcohols show intramolecular hydrogen bonding.

Answer

Answer: (c) Assertion (A) is correct, Reason (R) is wrong statement.


Question 38.
Assertion: Phenol undergoes Kolbe’s reaction but ethanol does not.
Reason: Phenol is more acidic than ethanol.

Answer

Answer: (b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).


Question 39.
Assertion: The C-O-C bond angle in ethers is higher than H-O-H bond angle in water.
Reason: Oxygen in both ethers and water is sp³ hybridised.

Answer

Answer: (b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).


Question 40.
Assertion: The boiling point of diethyl ether is much less than that of ethanol.
Reason: In ethanol, the molecules are associated by the formation of intermolecular hydrogen bonding, whereas in diethyl ether, it is not possible.

Answer

Answer: (a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).


Question 41.
Assertion: Alcohols have higher boiling points than ethers of comparable molecular masses.
Reason: Alcohols and ethers are isomeric compounds.

Answer

Answer: (b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).


Question 42.
Assertion: o- and p-nitrophenols can be separated by steam distillation.
Reason: o-isomer is steam volatile due to chelation, while p-isomer is not steam volatile due to association of molecules by intermolecular H-bonding.

Answer

Answer: (a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).


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MCQ Questions for Class 12 Chemistry Chapter 12 Aldehydes, Ketones and Carboxylic Acids with Answers

Students are advised to practice the NCERT MCQ Questions for Class 12 Chemistry Chapter 12 Aldehydes, Ketones and Carboxylic Acids with Answers Pdf free download is available here. MCQ Questions for Class 12 Chemistry with Answers are prepared as per the Latest Exam Pattern. Students can solve these Aldehydes, Ketones and Carboxylic Acids Class 12 MCQs Questions with Answers and assess their preparation level.

Aldehydes, Ketones and Carboxylic Acids Class 12 MCQs Questions with Answers

Solving the Aldehydes, Ketones and Carboxylic Acids Multiple Choice Questions of Class 12 Chemistry Chapter 12 MCQ can be of extreme help as you will be aware of all the concepts. These MCQ Questions on Aldehydes, Ketones and Carboxylic Acids Class 12 with answers pave for a quick revision of the Chapter thereby helping you to enhance subject knowledge. Have a glance at the MCQ of Chapter 12 Chemistry Class 12 and cross-check your answers during preparation.

Question 1.
Addition of water to alkynes occurs in acidic medium and in the presence of Hg2+ ions as a catalyst. Which of the following products will be formed on addition of water to but-1 -yne under these conditions?
MCQ Questions for Class 12 Chemistry Chapter 12 Aldehydes, Ketones and Carboxylic Acids with Answers 1

Answer

Answer:
MCQ Questions for Class 12 Chemistry Chapter 12 Aldehydes, Ketones and Carboxylic Acids with Answers 2


Question 2.
Which of the following compounds is most reactive towards nucleophilic addition reactions?
MCQ Questions for Class 12 Chemistry Chapter 12 Aldehydes, Ketones and Carboxylic Acids with Answers 3

Answer

Answer:
MCQ Questions for Class 12 Chemistry Chapter 12 Aldehydes, Ketones and Carboxylic Acids with Answers 4


Question 3.
The correct order of increasing acidic strength is
(a) Phenol < Ethanol < Chloroacetic acid < Acetic acid
(b) Ethanol < Phenol < Chloroacetic acid < Acetic acid
(c) Ethanol < Phenol < Acetic acid < Chloroacetic acid
(d) Chloroacetic acid < Acetic acid < Phenol < Ethanol

Answer

Answer: (c) Ethanol < Phenol < Acetic acid < Chloroacetic acid


Question 4.
Compound MCQ Questions for Class 12 Chemistry Chapter 12 Aldehydes, Ketones and Carboxylic Acids with Answers 5 can be prepared by the reaction of
(a) Phenol and benzoic acid in the presence of NaOH
(b) Phenol and benzoyl chloride in the presence of pyridine
(c) Phenol and benzoyl chloride in the presence of ZnCl2
(d) Phenol and benzaldehyde in the presence of palladium

Answer

Answer: (b) Phenol and benzoyl chloride in the presence of pyridine


Question 5.
The reagent which does not react with both, acetone and benzaldehyde.
(a) Sodium hydrogensulphite
(b) Phenyl hydrazine
(c) Fehling’s solution
(d) Grignard reagent

Answer

Answer: (c) Fehling’s solution


Question 6.
Cannizzaro’s reaction is not given by
MCQ Questions for Class 12 Chemistry Chapter 12 Aldehydes, Ketones and Carboxylic Acids with Answers 6
(c) HCHO
(d) CH3CHO

Answer

Answer: (d) CH3CHO


Question 7.
Which product is formed when the compound MCQ Questions for Class 12 Chemistry Chapter 12 Aldehydes, Ketones and Carboxylic Acids with Answers 7 is treated with concentrated aqueous KOH solution?
MCQ Questions for Class 12 Chemistry Chapter 12 Aldehydes, Ketones and Carboxylic Acids with Answers 8

Answer

Answer:
MCQ Questions for Class 12 Chemistry Chapter 12 Aldehydes, Ketones and Carboxylic Acids with Answers 9


Question 8.
MCQ Questions for Class 12 Chemistry Chapter 12 Aldehydes, Ketones and Carboxylic Acids with Answers 10
Structure of ‘A’ and type of isomerism in the above reaction are respectively.
(a) Prop-1-en-2-ol, metamerism
(b) Prop-1 -en-1 -ol, tautomerism
(c) Prop-2-en-2-ol, geometrical isomerism
(d) Prop-1-en-2-ol, tautomerism

Answer

Answer: (d) Prop-1-en-2-ol, tautomerism


Question 9.
Compounds A and C in the following reaction are
MCQ Questions for Class 12 Chemistry Chapter 12 Aldehydes, Ketones and Carboxylic Acids with Answers 11
(a) identical
(b) positional isomers
(c) functional isomers
(d) optical isomers

Answer

Answer: (b) positional isomers


Question 10.
Which is the most suitable reagent for the following conversion?
MCQ Questions for Class 12 Chemistry Chapter 12 Aldehydes, Ketones and Carboxylic Acids with Answers 12
(a) Tollen’s reagent
(b) Benzoyl peroxide
(c) l2 and NaOH solution
(d) Sn and NaOH solution

Answer

Answer: (c) l2 and NaOH solution


Question 11.
Which of the following compounds wilt give butanone on oxidation with alkaline KMnO4 solution?
(a) Butan-1-ol
(b) Butan-2-ol
(c) Both of these
(d) None of these

Answer

Answer: (b) Butan-2-ol


Question 12.
In Clemmensen Reduction carbonyl compound is treated with
(a) Zinc amalgam + HCl
(b) Sodium amalgam + HCl
(c) Zinc amalgam + nitric add
(d) Sodium amalgam + HNO3

Answer

Answer: (a) Zinc amalgam + HCl


Assertion and Reason Type Questions

The questions given below consist of an assertion and a reason. Use the following key to choose the appropriate answer.
(a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).
(b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).
(c) Assertion (A) is correct, Reason (R) is wrong statement.
(d) Assertion (A) is wrong, but Reason (R) is correct statement.

Question 13.
Assertion: Formaldehyde is a planar molecule.
Reason: It contains sp² hybridised carbon atom.

Answer

Answer: (a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).


Question 14.
Assertion: Compounds containing -CHO group are easily oxidised to corresponding carboxylic acids.
Reason: Carboxylic acids can be reduced to alcohols by treatment with LiAlH4.

Answer

Answer: (b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).


Question 15.
Assertion: The a-hydrogen atom in carbonyl compounds is less acidic.
Reason: The anion formed after the loss of α-hydrogen atom is resonance stabilised.

Answer

Answer: (d) Assertion (A) is wrong, but Reason (R) is correct statement.


Question 16.
Assertion: Aromatic aldehydes and formaldehyde undergo Cannizzaro reaction.
Reason: Aromatic aldehydes are almost as reactive as formaldehyde.

Answer

Answer: (c) Assertion (A) is correct, Reason (R) is wrong statement.


Question 17.
Assertion: Aldehydes and ketones, both react with Tollen’s reagent to form silver mirror.
Reason: Both, aldehydes and ketones contain a carbonyl group.

Answer

Answer: (d) Assertion (A) is wrong, but Reason (R) is correct statement.


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MCQ Questions for Class 12 Chemistry Chapter 13 Amines with Answers

Students are advised to practice the NCERT MCQ Questions for Class 12 Chemistry Chapter 13 Amines with Answers Pdf free download is available here. MCQ Questions for Class 12 Chemistry with Answers are prepared as per the Latest Exam Pattern. Students can solve these Amines Class 12 MCQs Questions with Answers and assess their preparation level.

Amines Class 12 MCQs Questions with Answers

Solving the Amines Multiple Choice Questions of Class 12 Chemistry Chapter 13 MCQ can be of extreme help as you will be aware of all the concepts. These MCQ Questions on Amines Class 12 with answers pave for a quick revision of the Chapter thereby helping you to enhance subject knowledge. Have a glance at the MCQ of Chapter 13 Chemistry Class 12 and cross-check your answers during preparation.

Question 1.
When a primary amine reacts with chloroform in ethanolic KOH, then the product is
(a) isocyanide
(b) aldehyde
(c) cyanide
(d) alcohol

Answer

Answer: (a) isocyanide


Question 2.
Which of the following does not react with Hinsberg reagent?
(a) C2H5NH2
(b) (C2H5)2NH
(c) (C2H5)3N
(d) CH3NH2

Answer

Answer: (c) (C2H5)3N


Question 3.
C6H5N2Cl + CuCN → C6H5CN + N2 + CuCl is
(a) Balz-Schiemann
(b) Gattermann reaction
(c) Simonini reaction
(d) Sandmeyer reaction

Answer

Answer: (d) Sandmeyer reaction


Question 4.
Which of the following is most basic?
(a) Benzylamine
(b) Aniline
(c) Acetanilide
(d) p-nitroaniline

Answer

Answer: (a) Benzylamine


Question 5.
Among the following which one is strongest base?
(a) Ammonia
(b) Methylamine
(c) Ethylamine
(d) None of these

Answer

Answer: (c) Ethylamine


Question 6.
Which of the following compound is the most basic?
MCQ Questions for Class 12 Chemistry Chapter 13 Amines with Answers 1

Answer

Answer:
MCQ Questions for Class 12 Chemistry Chapter 13 Amines with Answers 2


Question 7.
The IUPAC name of MCQ Questions for Class 12 Chemistry Chapter 13 Amines with Answers 3 is
(a) N-Ethyl- N-methylbenzenamine
(b) N-Methyl- N-ethylbenzenamine
(c) N, N-Ethyl methyl benzenamine
(d) N, N-Methyl ethyl benzenamine

Answer

Answer: (a) N-Ethyl- N-methylbenzenamine


Question 8.
Gabriel phthalimide reaction is used for the preparation of
(a) 1° amine
(b) 2° amine
(c) 3° amine
(d) all of these

Answer

Answer: (a) 1° amine


Question 9.
Which of the following compound will be formed when aniline reacts with H2SO4?
MCQ Questions for Class 12 Chemistry Chapter 13 Amines with Answers 4

Answer

Answer:
MCQ Questions for Class 12 Chemistry Chapter 13 Amines with Answers 5


Question 10.
Which one of the following is most basic?
(a) C6H5NH2
(b) NH3
(c) CH3CH2NH2
(d) CH3NH2

Answer

Answer: (c) CH3CH2NH2


Question 11.
C2H5NH2 + HNO2 → A, A is:
(a) C6H5OH
(b) C2H5NHOH
(c) C2H6
(d) C2H5NO2

Answer

Answer: (a) C6H5OH


Question 12.
MCQ Questions for Class 12 Chemistry Chapter 13 Amines with Answers 6
(a) Benzoic acid
(b) Aniline
(c) Benzonitrile
(d) Benzylamine

Answer

Answer: (a) Benzoic acid


Question 13.
CH3C ≡ MCQ Questions for Class 12 Chemistry Chapter 13 Amines with Answers 7 p will be?
(a) CH3CH2NC
(b) CH3CH2NH2
(c) CH3NHCH3
(d) CH3NH2

Answer

Answer: (b) CH3CH2NH2


Question 14.
Which of the following compound gives dye test?
(a) Aniline
(b) Methylamine
(c) Diphenylamine
(d) Ethylamine

Answer

Answer: (a) Aniline


Question 15.
Gabriel phthalimide reaction is used for the preparation of
(a) primary aromatic amines
(b) secondary amines
(c) aliphatic primary amines
(d) tertiary amines

Answer

Answer: (c) aliphatic primary amines


Question 16.
The IUPAC name of the compound
MCQ Questions for Class 12 Chemistry Chapter 13 Amines with Answers 8
(a) 2-Amino-4-ethyl-2-hydroxypent-4-ene
(b) 2-Amino – 4 – ethylpent – 4 – en – 2 – ol
(c) 4-Ethyl – 2 – hydroxypent -4-en – 2 – amine
(d) 2-Amino – 4 – methylhexan – 2 -ol

Answer

Answer: (b) 2-Amino – 4 – ethylpent – 4 – en – 2 – ol


Assertion and Reason Type Questions

The questions given below consist of an assertion and a reason. Use the following key to choose the appropriate answer.
(a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).
(b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).
(c) Assertion (A) is correct, Reason (R) is wrong statement.
(d) Assertion (A) is wrong, but Reason (R) is correct statement.

Question 17.
Assertion: Acylation of amines gives a monosubstituted product whereas alkylation of amines gives polysubstituted product.
Reason: Acyl group sterically hinders the approach of further acyl groups.

Answer

Answer: (c) Assertion (A) is correct, Reason (R) is wrong statement.


Question 18.
Assertion: Hoffmann’s bromamide reaction is given by primary amines.
Reason: Primary amines are more basic than secondary amines.

Answer

Answer: (c) Assertion (A) is correct, Reason (R) is wrong statement.


Question 19.
Assertion: N-Ethylbenzene sulphonamide is soluble in alkali.
Reason: Hydrogen attached to nitrogen in sulphonamide is strongly acidic.

Answer

Answer: (a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).


Question 20.
Assertion: N, N-Diethylbenzene sulphonamide is insoluble in alkali.
Reason: Sulphonyl group attached to nitrogen atom is strong electron withdrawing group.

Answer

Answer: (b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).


Question 21.
Assertion: Only a small amount of HCl is required in the reduction of nitro compounds with iron scrap and HCl in the presence of steam.
Reason: FeCl2 formed gets hydrolysed to release HCl during the reaction.

Answer

Answer: (a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).


Question 22.
Assertion: Aliphatic 1° amines can be prepared by Gabriel phthalimide synthesis.
Reason: Aryl halides undergo nucleophilic substitution with anion formed by phthalimide.

Answer

Answer: (c) Assertion (A) is correct, Reason (R) is wrong statement.


Question 23.
Assertion: Acetanilide is less basic than aniline.
Reason: Acetylation of aniline results in decrease of electron density on nitrogen.

Answer

Answer: (a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).


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MCQ Questions for Class 12 Chemistry Chapter 14 Biomolecules with Answers

Students are advised to practice the NCERT MCQ Questions for Class 12 Chemistry Chapter 14 Biomolecules with Answers Pdf free download is available here. MCQ Questions for Class 12 Chemistry with Answers are prepared as per the Latest Exam Pattern. Students can solve these Biomolecules Class 12 MCQs Questions with Answers and assess their preparation level.

Biomolecules Class 12 MCQs Questions with Answers

Solving the Biomolecules Multiple Choice Questions of Class 12 Chemistry Chapter 14 MCQ can be of extreme help as you will be aware of all the concepts. These MCQ Questions on Biomolecules Class 12 with answers pave for a quick revision of the Chapter thereby helping you to enhance subject knowledge. Have a glance at the MCQ of Chapter 14 Chemistry Class 12 and cross-check your answers during preparation.

Question 1.
The linkage which holds various amino acid units in primary structure of proteins is
(a) glycosidic linkage
(b) hydrogen bond
(c) peptide linkage
(d) ionic bond

Answer

Answer: (c) peptide linkage


Question 2.
Vitamin A is called
(a) Ascorbic acid
(b) Retinol
(c) Calciferol
(d) Tocoferol

Answer

Answer: (b) Retinol


Question 3.
The deficiency of vitamin B1 causes which disease?
(a) Beriberi
(b) Rickets
(c) Anaemia
(d) Xerosis

Answer

Answer: (a) Beriberi


Question 4.
Deficiency of vitamin C causes
(a) Scurvy
(b) Rickets
(c) Anaemia
(d) None of these

Answer

Answer: (a) Scurvy


Question 5.
An example of non-reducing sugar is
(a) Sucrose
(b) Lactose
(c) Maltose
(d) None

Answer

Answer: (a) Sucrose


Question 6.
Which of the following is not an essential amino acid?
(a) Glycine
(b) Lysine
(c) Phenyl alanine
(d) Valine

Answer

Answer: (a) Glycine


Question 7.
Which of the following is a water-soluble vitamin?
(a) Vitamin E
(b) Vitamin K
(c) Vitamin B
(d) Vitamin A

Answer

Answer: (c) Vitamin B


Question 8.
Vitamin B1 is
(a) Riboflavin
(b) Cobalamin
(c) Thiamine
(d) Pyridoxine

Answer

Answer: (c) Thiamine


Question 9.
Which is sweetest of the following:
(a) Sucrose
(b) Glucose
(c) Fructose
(d) Maltose

Answer

Answer: (c) Fructose


Question 10.
Rickets may be caused by the deficiency of which vitamin?
(a) Vitamin D
(b) Vitamin C
(c) Vitamin A
(d) Vitamin B

Answer

Answer: (a) Vitamin D


Question 11.
The function of enzymes in the living system is to
(a) Maintain pH
(b) Catalyse biochemical process
(c) provide immunity
(d) transport oxygen

Answer

Answer: (b) Catalyse biochemical process


Question 12.
The disaccharide present in milk is
(a) sucrose
(b) maltose
(c) lactose
(d) cellulose

Answer

Answer: (c) lactose


Question 13.
Which base is present in RNA but not in DNA?
(a) Uracil
(b) Cytosine
(c) Guanine
(d) Thymine

Answer

Answer: (a) Uracil


Question 14.
In aqueous solution, an amino acid exists as
(a) cation
(b) anion
(c) dianion
(d) zwitterion

Answer

Answer: (d) zwitterion


Question 15.
Which of the following is stored in liver of animals?
(a) Amylose
(b) Cellulose
(c) Amylopectin
(d) Glycogen

Answer

Answer: (d) Glycogen


Question 16.
Which of the following is a polysaccharide?
(a) Maltose
(b) Sucrose
(c) Fructose
(d) Cellulose

Answer

Answer: (d) Cellulose


Question 17.
The Vitamin responsible for the coagulation of blood is:
(a) Vitamin B1
(b) Vitamin D
(c) Vitamin K
(d) Vitamin C

Answer

Answer: (c) Vitamin K


Question 18.
Which one is the complimentary base of adenine in one strand to that in the other strand of DNA?
(a) Cytosine
(b) Guanine
(c) Uracil
(d) Thymine

Answer

Answer: (d) Thymine


Question 19.
Ribose is a
(a) monosaccharide
(b) polysaccharide
(c) polypeptide
(d) disaccharide

Answer

Answer: (a) monosaccharide


Question 20.
In which of the following order base, phosphate and sugar are arranged in the nucleotide of DNA?
(a) Base-phosphate-sugar
(b) Base-sugar-phosphate
(c) Phosphate-base-sugar
(d) Sugar-base-phosphate

Answer

Answer: (b) Base-sugar-phosphate


Assertion and Reason Type Questions

The questions given below consist of an assertion and a reason. Use the following key to choose the appropriate answer.
(a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).
(b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).
(c) Assertion (A) is correct, Reason (R) is wrong statement.
(d) Assertion (A) is wrong, but Reason (R) is correct statement.

Question 21.
Assertion: D (+) – Glucose is dextrorotatory in nature.
Reason: ‘D’ represents its dextrorotatory nature.

Answer

Answer: (c) Assertion (A) is correct, Reason (R) is wrong statement.


Question 22.
Assertion: Vitamin D can be stored in our body.
Reason: Vitamin D is fat-soluble vitamin.

Answer

Answer: (a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).


Question 23.
Assertion: ß-glycosidic linkage is present in maltose,
MCQ Questions for Class 12 Chemistry Chapter 14 Biomolecules with Answers 1
Reason: Maltose is composed of two glucose units in which C-1 of one glucose unit is linked to C-4 of another glucose unit.

Answer

Answer: (d) Assertion (A) is wrong, but Reason (R) is correct statement.


Question 24.
Assertion: All naturally occurring α-aminoacids except glycine are optically active.
Reason: Most naturally occurring amino acids have L-configuration.

Answer

Answer: (b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).


Question 25.
Assertion: Deoxyribose, C5H10O4 is a carbohydrate.
Reason: Carbohydrates are hydrates of carbon so compounds which follow Cx(H2O)y formula are carbohydrates.

Answer

Answer: (c) Assertion (A) is correct, Reason (R) is wrong statement.


Question 26.
Assertion: Glycine must be taken through diet.
Reason: It is a non-essential amino acid.

Answer

Answer: (d) Assertion (A) is wrong, but Reason (R) is correct statement.


Question 27.
Assertion: In the presence of enzyme, substrate molecule can be attacked by the reagent effectively.
Reason: Active sites of enzymes hold the substrate molecule in a suitable position.

Answer

Answer: (a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).


Question 28.
Assertion: The two strands in double strand helix structure of DNA are complementary to each other.
Reason: Disulphide bonds are formed between specific pairs of bases.

Answer

Answer: (c) Assertion (A) is correct, Reason (R) is wrong statement.


Question 29.
Assertion: Glucose reacts with hydroxylamine to form an oxime and also adds a molecule of hydrogen cyanide to give cyanohydrin.
Reason: The carbonyl group is present in the open chain structure of glucose.

Answer

Answer: (a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).


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